Relaxation is a Two-Step Process for Metallic Glasses

Anelastic Relaxation of Metallic Glasses

Relaxation of bulk metallic glasses studied by mechanical spectroscopy.

The relaxational dynamics in metallic glasses (MGs) is investigated by using mechanical spectroscopy. The spectra show that in MGs there are two relaxations: (i) the α relaxation, linked to the glass transition, as observed in other classes of amorphous materials; and (ii) the β relaxation, well observed below the glass transition, with an intensity strongly dependent on the MG composition, the...

Structural relaxation of Ti-based bulk metallic glasses

The enthalpy relaxation behavior of Ti41.5Cu37.5Ni7.5Zr2.5Hf5Sn5Si1 bulk metallic glass (BMG) was investigated in this study. It is found that relaxation behavior follows the general characteristics for amorphous materials: the annealing time dependence of recovery enthalpy follows a stretched exponential function with the mean relaxation time obeying an Arrhenius law. In addition, the equilibr...

Structural relaxation kinetics defines embrittlement in metallic glasses

Article history: Received 5 December 2017 Received in revised form 22 January 2018 Accepted 23 January 2018 Available online xxxx Structural relaxation during isothermal annealing, quantified by enthalpy recovery of Zr44Ti11Cu10Ni10Be25 towards its metastable equilibrium and correlation to embrittlement, quantified through fracture toughness, KQ, is studied. Enthalpy relaxation over time obeys ...

Pronounced slow β-relaxation in La-based bulk metallic glasses.

Most metallic glasses (MGs) exhibit weak evidence of slow β-relaxation in their dynamic mechanical spectroscopy spectra. In contrast to other MGs, the La-based MGs we report here show a distinct slow β-relaxation peak in the mechanical relaxation measurements. We find that the slow β-relaxation behavior can be tuned by modification of the chemical composition and fragility. The structural origi...